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05/16專題演講公告

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演講人刁維光 博士

演講題目:鈣鈦礦太陽能電池 Perovskite Solar Cells

 20160510

演講人刁維光 博士

服務單位:交通大學應化系

演講題目:鈣鈦礦太陽能電池 Perovskite Solar Cells

演講時間:105.05.16 10:20~12:10

演講地點:工綜館203室

 

演講摘要:The development of all solid-state thin-film solar cells has reached a new milestone when the devices made of organometallic lead halide perovskite materials were reported with power conversion efficiency (PCE) exceeding 20 %. The key issue to make a device with a great photovoltaic performance for this kind of solar cells is to control the film morphology of perovskite under different experimental conditions. Varied mesoporous TiO2 nanostructures were applied to show the morphological effect of the scaffold on the device performance with a mesoscopic heterojuction. Anti-solvent method was applied to improve the morphology and crystallinity of the perovskite films to obtain device performance exceeding PCE 16 %. Varied additives were applied to control the formation morphology of the perovskite nanocrystals with a planar heterojunction. Moreover, we developed a simple drop-casting method via solvent-solvent extraction to grow dense and uniform perovskite nanocrystals at room temperature for carbon-based mesoscopic solar cells free of an organic hole-transport layer. The device performance attained an efficiency 13.3 % of power conversion (PCE), which is significantly greater than that of DMF (6.3 %) and NMP (8.3 %) devices using traditional thermal annealing. For tin-rich perovskite, we designed and synthesized alloyed Sn-Pb mixed halide perovskites by dipping the precursor solutions on the mesoporous films with the TiO2/Al2O3/C configuration to form solar cells free of organic HTM. When 30 mol% of SnF2 additive was added in the tin-rich mix halide precursor solution, the device performance was improved from PCE 2.2 % (without SnF2) to PCE 4.3 % (with SnF2) with little effect of hysteresis.                                               

 

個人學經歷:

 

學歷

 

畢業學校

國別

主修學門系所

學位

國立清華大學

臺灣

化學系

學士 (1985)

國立清華大學

臺灣

化學系

博士 (1991)

 

經歷:

 

服務機關

服務部門

職稱

現職:國立交通大學

應用化學系()

特聘教授

經歷:國立交通大學

應用化學系()

教授

國立交通大學

應用化學系()

副教授

國立交通大學

應用化學系()

助理教授